On the ionization energy of CF3SF5 in the valence region measured by angle-resolved photoelectron spectroscopy
Journal of Electron Spectroscopy and Related Phenomena 152 巻 1-2 号
96-99 頁
2006-06 発行
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| ファイル情報(添付) | |
| タイトル ( eng ) |
On the ionization energy of CF3SF5 in the valence region measured by angle-resolved photoelectron spectroscopy
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| 作成者 |
Ibuki T.
Tamenori Y.
Takemoto M.
Nagaoka S.
Morishita Y.
Suzuki I.H.
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| 収録物名 |
Journal of Electron Spectroscopy and Related Phenomena
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| 巻 | 152 |
| 号 | 1-2 |
| 開始ページ | 96 |
| 終了ページ | 99 |
| 抄録 |
Ionization energies for valence electrons of CF3SF5 were measured in the 12-35 eV region by means of angle-resolved photoelectron spectroscopy. The observed ionization energies were basically consistent with previous ones measured by threshold photoelectron and HeI photoelectron spectroscopy, and the ionization levels at 22.60, 26.92 and 27.86 eV were newly observed. Asymmetry parameter derived at hν = 684.7 eV was a constant of β = 1.02 ± 0.04 in the ionization energy lower than 20 eV, suggesting that lone pair electron of F atom is probably released through 2p → εd like electron emission. Characters of the 22 valence bands were elucidated with the help of ab initio calculations and of the nature of valence orbitals for CF4 and SF6
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| 著者キーワード |
Angle-resolved photoelectron spectroscopy
Asymmetry parameter
Ionization energy
Valence orbital
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| NDC分類 |
化学 [ 430 ]
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Elsevier B.V.
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| 発行日 | 2006-06 |
| 権利情報 |
Copyright (c) 2006 Elsevier B.V.
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| 出版タイプ | Author’s Original（十分な品質であるとして、著者から正式な査読に提出される版） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[ISSN] 0368-2048
[DOI] 10.1016/j.elspec.2006.03.009
[NCID] AA00697082
[DOI] http://dx.doi.org/10.1016/j.elspec.2006.03.009
～の異版である
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