Biotransformation of sesquiterpenoids having α,β-unsaturated carbonyl groups with cultured plant cells of Marchantia polymorpha
Journal of Molecular Catalysis B: Enzymatic Volume 39 Issue 1-4
Page 13-17
published_at 2006-05
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| File | |
| Title ( eng ) |
Biotransformation of sesquiterpenoids having α,β-unsaturated carbonyl groups with cultured plant cells of Marchantia polymorpha
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| Creator |
Hegazy Mohamed-Elamir F.
Kuwata Chika
Ahmed Ahmed A.
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| Source Title |
Journal of Molecular Catalysis B: Enzymatic
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| Volume | 39 |
| Issue | 1-4 |
| Start Page | 13 |
| End Page | 17 |
| Abstract |
The biotransformation of sesquiterpenoids having an α,β-unsaturated carbonyl group, such as -santonin (1), lancerodiol p-hydroxybenzoate (2), 8,9-dehydronootkatone (3) and nootkatone (4), with cultured suspension cells of Marchantia polymorpha was investigated. It was found that the C-C double bond of 1 and 2 was hydrogenated to give 1,2-dihydro--santonin (5) and 3,4-dihydrolancerodiol p-hydroxybenzoate (6), respectively, while the allylic position of the C-C double bond of 3 and 4 was hydroxylated to give 13-hydroxy-8,9-dehydronootkatone (7) and 9-hydroxynootkatone (8), respectively.
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| Keywords |
Biotransformation
Marchantia polymorpha
Hydrogenation
Hydroxylation
α-Santonin
Lancerodiol p-hydroxybenzoate
8,9-Dehydronootkatone
Nootkatone
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B.V.
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| Date of Issued | 2006-05 |
| Rights |
Copyright (c) 2006 Elsevier B.V.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 1381-1177
[DOI] 10.1016/j.molcatb.2006.01.032
[NCID] AA11069296
[DOI] http://dx.doi.org/10.1016/j.molcatb.2006.01.032
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