Positive charge distribution in (benzene)1(toleune)2+ and (benzene)2(toluene)1+ studied by photodissociation spectroscopy

Journal of Chemical Physics Volume 117 Issue 23 Page 10648-10653 published_at 2002-12
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Title ( eng )
Positive charge distribution in (benzene)1(toleune)2+ and (benzene)2(toluene)1+ studied by photodissociation spectroscopy
Creator
Ohashi Kazuhiko
Nishi Nobuyuki
Source Title
Journal of Chemical Physics
Volume 117
Issue 23
Start Page 10648
End Page 10653
Abstract
The electronic and vibrational spectra of the benzene-toluene heterotrimer ions, B1T2+ and B2T1+, were observed using the tunable near-infrared and infrared lasers and the tandem mass spectrometer. The electronic spectra of both ions display the CR band, demonstrating that the positive charge is not localized on one molecule. The results were explained by the CR interaction between B2 and T.
NDC
Chemistry [ 430 ]
Language
eng
Resource Type journal article
Publisher
American Institute of Physics
Date of Issued 2002-12
Rights
Copyright (c) 2002 American Institute of Physics
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 0021-9606
[DOI] http://dx.doi.org/10.1063/1.1521126 isVersionOf