Intracluster proton transfer in aniline-amine complex ions
Chemical Physics Letters Volume 359 Issue 3-4
Page 283-288
published_at 2002
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| File | |
| Title ( eng ) |
Intracluster proton transfer in aniline-amine complex ions
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| Creator |
Ohashi Kazuhiko
Honkawa Yoshiki
Nishi Nobuyuki
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| Source Title |
Chemical Physics Letters
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| Volume | 359 |
| Issue | 3-4 |
| Start Page | 283 |
| End Page | 288 |
| Abstract |
The intracluster proton transfer in aniline-amine complex ions is investigated by infrared photodissociation spectroscopy and density functional theory calculations. The proton acceptors include ammonia, methylamine, dimethylamine and trimethylamine in ascending order of proton affinity. The spectra of (aniline-ammonia)+ and (aniline-methylamine)+ demonstrate the persistence of the aniline ion unit in the complexes. For (aniline-dimethylamine)+ and (aniline-trimethylamine)+, the spectra imply the transformation to the anilino radical (C6H5NH) unit, suggesting the occurrence of the proton transfer.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier B. V.
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| Date of Issued | 2002 |
| Rights |
Copyright (c) 2002 Elsevier B.V.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] http://dx.doi.org/10.1016/S0009-2614(02)00737-6
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