Structures of [Mg·(H2O)1,2]+ and [Al·(H2O)1,2]+ ions studied by infrared photodissociation spectroscopy: Evidence of [HO-Al-H]+ ion core structure in [Al·(H2O)2]+
Chemical Physics Letters Volume 390 Issue 1-3
Page 140-144
published_at 2004-05
アクセス数 : 1052 件
ダウンロード数 : 288 件
今月のアクセス数 : 16 件
今月のダウンロード数 : 7 件
この文献の参照には次のURLをご利用ください : https://ir.lib.hiroshima-u.ac.jp/00014690
| File | |
| Title ( eng ) |
Structures of [Mg·(H2O)1,2]+ and [Al·(H2O)1,2]+ ions studied by infrared photodissociation spectroscopy: Evidence of [HO-Al-H]+ ion core structure in [Al·(H2O)2]+
|
| Creator |
Ohshimo Keijiro
Misaizu Fuminori
Nishi Nobuyuki
|
| Source Title |
Chemical Physics Letters
|
| Volume | 390 |
| Issue | 1-3 |
| Start Page | 140 |
| End Page | 144 |
| Abstract |
Infrared spectra of [Mg·(H2O)1,2]+ and [Al·(H2O)1,2]+ are measured in the OH stretching region (3200-3800 cm-1). The spectra show the symmetric and asymmetric OH stretching bands of water molecules that are directly bound to the metal ions through metal-oxygen intermolecular bonds. In addition to these bands, the [Al·(H2O)2]+ ion has another band at 3714 cm-1. This band is assigned to the free OH stretching vibration of the [HO-Al-H]+ ion; the aluminum ion is inserted into the O-H bond of one water molecule in [Al·(H 2O)2]+.
|
| NDC |
Chemistry [ 430 ]
|
| Language |
eng
|
| Resource Type | journal article |
| Publisher |
Elsevier B.V.
|
| Date of Issued | 2004-05 |
| Rights |
Copyright (c) 2004 Elsevier B.V.
|
| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0009-2614
[DOI] 10.1016/j.cplett.2004.03.148
[DOI] http://dx.doi.org/10.1016/j.cplett.2004.03.148
isVersionOf
|
