Asymmetric nuclear motion of the F 1s–ionized state in BF3 probed by quadruple-ion-coincidence momentum imaging
Physical review A Volume 69 Issue 2
Page 022506-1-022506-4
published_at 2004
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Title ( eng ) |
Asymmetric nuclear motion of the F 1s–ionized state in BF3 probed by quadruple-ion-coincidence momentum imaging
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Creator |
Fanis A.De
Saito N.
Machida M.
Chiba H.
Cassimi A.
Dörner R.
Kayano I.
Ueda K.
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Source Title |
Physical review A
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Volume | 69 |
Issue | 2 |
Start Page | 022506-1 |
End Page | 022506-4 |
Abstract |
Using the quadruple-ion-coincidence momentum imaging technique, we find that the momentum correlation of the four atomic ions departed from one BF34+ parent molecular ion produced via multiple Auger decay after F 1s ionization exhibits asymmetric fragmentation in which the B+ ion is ejected in the direction opposite to one of the F+ ions. This observation provides evidence of symmetry lowering, from D3h to C3v in the F 1s–ionized state.
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NDC |
Physics [ 420 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
The American Physical Society
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Date of Issued | 2004 |
Rights |
Copyright (c) 2004 The American Physical Society
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Publish Type | Version of Record |
Access Rights | open access |
Source Identifier |
[ISSN] 1050-2947
[DOI] 10.1103/PhysRevA.69.022506
[DOI] http://dx.doi.org/10.1103/PhysRevA.69.022506
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