Symmetry-Resolved Vibrational Spectroscopy for the C 1s[-1]2πu Renner-Teller Pair States in CO2
Physical review letters Volume 88 Issue 8
Page 083001-1-083001-4
published_at 2002-02-25
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| File | |
| Title ( eng ) |
Symmetry-Resolved Vibrational Spectroscopy for the C 1s[-1]2πu Renner-Teller Pair States in CO2
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| Creator |
Yoshida H.
Nobusada K.
Tanimoto S.
Saito N.
Fanis A. De
Ueda K.
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| Source Title |
Physical review letters
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| Volume | 88 |
| Issue | 8 |
| Start Page | 083001-1 |
| End Page | 083001-4 |
| Abstract |
Symmetry-resolved excitation spectra have been measured for the Renner-Teller pair states A1 and B1 split from the core-excited C 1s[-1]2πu state in CO2. A vibrational progression with the spacings of ∼145 meV is found in both the A1 and B1 spectra at different energies and assigned to the symmetric stretching mode caused in the B1 linear state, with the help of ab initio calculations. Appearance of the vibrations in the A1 spectrum is interpreted as due to nonadiabatic coupling between the A1 and B1 states via the bending motion.
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
The American Physical Society
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| Date of Issued | 2002-02-25 |
| Rights |
Copyright (c) 2002 The American Physical Society
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0031-9007
[DOI] 10.1103/PhysRevLett.88.083001
[DOI] http://dx.doi.org/10.1103/PhysRevLett.88.083001
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