NMR evidence for Mott-Hubbard localization in (NH3)K3C60

Physical review. Third series. B, Condensed matter and materials physics Volume 62 Issue 2 Page R775-R778 published_at 2000-07-01
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Title ( eng )
NMR evidence for Mott-Hubbard localization in (NH3)K3C60
Creator
Tou Hideki
Maniwa Y.
Iwasa Y.
Shimoda H.
Mitani T.
Source Title
Physical review. Third series. B, Condensed matter and materials physics
Volume 62
Issue 2
Start Page R775
End Page R778
Abstract
13C, 1H, and 39K-NMR measurements of (NH3)K3C60 unambiguously demonstrated that its magnetic properties are described as a S=1/2 localized spin system over the entire temperature range (300 K–4.2 K). A possible antiferromagnetic structure that appeared below 45 K is compatible with the orientational order of K-NH3 pairs on the octahedral (O) site. The present NMR study strongly suggests that the Mott-Hubbard localization occurs due to the removal of the C60 t1u-orbital degeneracy.
NDC
Physics [ 420 ]
Language
eng
Resource Type journal article
Publisher
The American Physical Society
Date of Issued 2000-07-01
Rights
Copyright (c) 2000 The American Physical Society
Publish Type Version of Record
Access Rights open access
Source Identifier
[ISSN] 1098-0121
[DOI] http://dx.doi.org/10.1103/PhysRevB.62.R775 isVersionOf