NMR evidence for Mott-Hubbard localization in (NH3)K3C60
Physical review. Third series. B, Condensed matter and materials physics Volume 62 Issue 2
Page R775-R778
published_at 2000-07-01
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Title ( eng ) |
NMR evidence for Mott-Hubbard localization in (NH3)K3C60
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Creator |
Tou Hideki
Maniwa Y.
Iwasa Y.
Shimoda H.
Mitani T.
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Source Title |
Physical review. Third series. B, Condensed matter and materials physics
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Volume | 62 |
Issue | 2 |
Start Page | R775 |
End Page | R778 |
Abstract |
13C, 1H, and 39K-NMR measurements of (NH3)K3C60 unambiguously demonstrated that its magnetic properties are described as a S=1/2 localized spin system over the entire temperature range (300 K–4.2 K). A possible antiferromagnetic structure that appeared below 45 K is compatible with the orientational order of K-NH3 pairs on the octahedral (O) site. The present NMR study strongly suggests that the Mott-Hubbard localization occurs due to the removal of the C60 t1u-orbital degeneracy.
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NDC |
Physics [ 420 ]
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Language |
eng
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Resource Type | journal article |
Publisher |
The American Physical Society
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Date of Issued | 2000-07-01 |
Rights |
Copyright (c) 2000 The American Physical Society
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Publish Type | Version of Record |
Access Rights | open access |
Source Identifier |
[ISSN] 1098-0121
[DOI] http://dx.doi.org/10.1103/PhysRevB.62.R775
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