Comparing α-carbanion-stabilizing ability of substituents using the Brook rearrangement
Tetrahedron letters Volume 39 Issue 29
Page 5243-5246
published_at 1998-07-16
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| File | |
| Title ( eng ) |
Comparing α-carbanion-stabilizing ability of substituents using the Brook rearrangement
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| Creator |
Ubayama Haruka
Sano Ayako
Yoshii Eiichi
Koizumi Toru
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| Source Title |
Tetrahedron letters
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| Volume | 39 |
| Issue | 29 |
| Start Page | 5243 |
| End Page | 5246 |
| Abstract |
The α-carbanion-stabilizing ability of the phenylthio and trimethylsilyl groups was compared based on the relative rate of the base-catalyzed Brook rearrangement of the β-substituted α-silylallylalcohol.
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| Keywords |
Carbanions
Rearrangements
Silicon and Compounds
Substituent effects
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| NDC |
Chemistry [ 430 ]
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| Language |
eng
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| Resource Type | journal article |
| Publisher |
Elsevier Science Ltd.
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| Date of Issued | 1998-07-16 |
| Rights |
Copyright (c) 1998 Elsevier Science Ltd.
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
[ISSN] 0040-4039
[DOI] 10.1016/S0040-4039(98)01032-6
[DOI] http://dx.doi.org/10.1016/S0040-4039(98)01032-6
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