Cement generations and diagenetic history of the upper Ordovician Cliefden Caves Limestone Group of New South Wales, Australia

Diagenetic features of the upper Ordovician (Caradocian) Cliefden Caves Limestone Group (N. S. W., Australia) were studied by the cathodoluminescence (CL) method, and their relation with depositional environments was discussed. The Cliefden Caves Limestone Group was deposited on a shallow marine carbonate platform developed on a volcanic island. The limestone succession reveals intertidal-subtidal lithofacies and consists of the Fossil Hill, Belubula, and Vandon Limestones, in ascending order. The Fossil Hill Limestone mostly consists of bedded limestone rich in brachiopods and sedentary organisms. The Belubula Limestone is a typical Middle-Upper Ordovician peritidal succession with syn-depositional dolomite and silicified fossil grains. The Vandon Limestone consists of fossiliferous stratified limestone occasionally containing red brown argillaceous limestone beds.
The Cliefden Caves Limestone Group was subjected to various diagenetic processes. The investigation of CL is the best or only method to differentiate the diagenetic products. There are at least three cementation stages and a dissolution stage. The cements of the first stage are mainly dull fine-grained (10-30 µm) calcite crystals fringing inter- and intra-granular porosity, which typically indicate a marine phreatic environment. In some specimens of the Belubula Limestone, cement of the first generation exhibits meniscus fabrics suggesting precipitation in a marine vadose environment. The dissolution formed both molds of aragonitic skeletal grains and fabric-unrelated void spaces which can exceed several cm in diameter. Lack of the first generation cement within the dissolution voids indicates that the dissolution postdated the marine cementation. After the dissolution stage, the second cementation precipitated granular calcite crystals composed of non-luminescence, dull, and bright zones in the peripheral order. The relative thickness of non-luminescence and bright zones probably related with a redox condition during their diagenesis. The last generation of cements formed in a deep burial environment, is normally dull and filled almost all remained porosity. This diagenetic history fits to the change of depositional environment which may have been controlled by both of local and global environmental settings.