Asymmetric Synthesis Using Novel Cationic Diether-Coordinated Lewis Acid and Stereoselective Synthesis of Piperidones and 1,2-Amino Alcohols
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| ID | 31887 |
| 本文ファイル | |
| 別タイトル | 新規でカチオニックなジエーテルを配位子とするルイス酸を用いた不斉合成とピペリドンおよび1,2-アミノアルコールの立体選択的合成
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| 著者 |
石丸 香緒里
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| NDC |
化学
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| 目次 | CONTENTS
Chapter 1.Asymmetric Synthesis Using Novel Cationic Diether-Coordinated Lewis Acids 1-1.Introduction / p1 1-2.Cationic Lewis Acids for [4+2]Type Cycloaddition of α-Chiral Aldimines / p12 1-3.Development of Novel Cationic Lewis Acids Coordinated by a Chiral Diether Ligand / p18 1-4.Attempt to Develop Novel Lewis Acids Bearinga Monoether-Coordinated Ligand / p31 1-5.Aldol Reaction by Using the Novel Cationic Lewis Acids / p39 1-6.Synthesis of the Modified Chiral Ligands / p44 1-7.Structure of Chiral Diether-Coordinated Titanium Complexes / p47 1-8.Summary / p51 1-9.Experimental Section / p52 1-10.References / p74 Chapter 2.Stereocontrol in [4+2]Type Cycloaddition of Imines Bearing α-Hydrogens with 2-Silyloxy-l,3-butadienes 2-1.Introduction / p77 2-2.[4+2]Type Cycloaddition of Imines bearing a-Hydrogens / p82 2-3.[4+2]Type Cycloaddition of ct-Silyloxyimines / p84 2-4.Summary / p98 2-5.Experimental Section / p99 2-6.References / p122 Chapter 3.Stereoselective Synthesis of 1,2-Amino Alcohols by Nucleophilic Addition of Organometallic Reagents to α-Silyloxyimines 3-1.Introduction / p124 3-2.Nucleophilic Addition of Organometallic Reagents to an α-Silyloxyimines / p131 3-3.Summary / p138 3-4.Experimental Section / p139 3-5.References / p150 |
| SelfDOI | |
| 言語 |
英語
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| NII資源タイプ |
学位論文
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| 広大資料タイプ |
学位論文
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| DCMIタイプ | text
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| フォーマット | application/pdf
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| 著者版フラグ | ETD
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| 権利情報 | Copyright(c) by Author
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| 関連情報(references) | 1* Kin-ya Akiba, Toshihiro Motoshima, Kaori Ishimaru, Kazutaka Watanabe, Hiroshi Hirota and Yohsuke Yamamoto. [4+2]Type Cycloaddition of Aldimines Bearing α-Hydrogens with 2-Silyloxy-1,3-butadienes Catalyzed by Trimethylsilyl Triflate, Synlett, 1993, 657-659.
2* Kaori Ishimaru, Kazutaka Watanabe, Yohsuke Yamamoto and Kin-ya Akiba. Stereocontrol in [4+2]Type Cycloaddition of an Aldimine Derived from (S)-Ethyl Lactate with 2-Silyloxy-1,3-butadienes, Synlett, 1994, 495-498.
3* Kaori Ishimaru, Kazutaka Tsuru, Katsunori Yabuta, Makoto Wada, Yohsuke Yamamoto and Kin-ya Akiba. Stereoselective Synthesis of 1,2-Amino Alcohols by Addition of Organocuprate• BF3 Complexes and Organolithium Reagents to an α-Silyloxyaldimine Derived from (S)-Ethyl Lactate, Tetrahedron, 1996, 52, 13137-13144.
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| 関連情報URL(references) | http://dx.doi.org/10.1016/0040-4020(96)00776-4
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| 学位記番号 | 甲第1582号
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| 授与大学 | 広島大学(Hiroshima University)
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| 学位名 | 博士(理学)
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| 学位名の英名 | Physical Science
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| 学位の種類の英名 | doctoral
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| 学位授与年月日 | 1997-03-25
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| 部局名 |
理学研究科
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