Stereochmistry of Tetra- and Pentacoordinate Organic Compounds of Phosphorus and Antimony
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| ID | 31858 |
| 本文ファイル | |
| 別タイトル | 4配位および5配位有機リンおよびアンチモン化合物の立体化学
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| 著者 | |
| NDC |
化学
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| 目次 | Contents
General Introduction / p1 References / p18 Chapter1.Preparation of Optically Active Phosphine Oxides via Wittig Type Rearrangement and Phosphine Sulfides via Alkylation of Lithium Phosphinothioites. 1.Introduction / p21 2.Results and Discussion / p25 3.Experimental / p50 4.References / p70 Chapter2.Characterization of the FirstEnantiomericPairs of Stereochemically Definable Hypervalent 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus. 1.Introduction / p72 2.Results and Discussion / p74 3.Experimental / p97 4.References / p108 Chapter3.The First Stereochemical Characterization of Configurationally Stable Diastereomers of Hypervalent 10-Sb-5 Stiboranes and Acceleration of Intramolecular Permutation by Donor Solvents 1.Introduction / p110 2.Results and Discussion / p112 3.Experimental / p137 4.References / p142 List of Publications / p145 |
| SelfDOI | |
| 言語 |
英語
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| NII資源タイプ |
学位論文
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| 広大資料タイプ |
学位論文
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| DCMIタイプ | text
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| フォーマット | application/pdf
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| 著者版フラグ | ETD
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| 権利情報 | Copyright(c) by Author
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| 関連情報(references) | *(1) The Wittig Rearrangement of Chiral Phosphinothioates Induced by the Tin-Lithium Transmetallation. Kawashima, T.; Kojima, S.; Miyake, T.; Inamoto, N. Tetrahedron Lett. 1989, 201-204.
*(2) The Optically Active Phosphinodithioates. Synthesis and Conversion to Optically Active Phosphine Sulfides. Kawashima, T.; Kojima, S.; Inamoto, N. Chem. Lett. 1989, 849-852.
*(3) Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex. Akiba, K.-y.; Nakata, H.; Yamamoto, Y.; Kojima, S. Chem. Lett. 1992, 1559-1562.
(4) Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes. Akiba, K.-y. ; Ito, Y.; Kondo, F.; Ohashi, N.; Sakaguchi, A.; Kojima, S.; Yamamoto, Y. Chem. Lett. 1992, 1562-1566.
(5) 121Sb Mossbauer Spectra of Hexafluorocumyl Alcohol Complexes of Sb(V) and of Sb(III) with Negative Quadrupole Coupling Constants. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y. Chem. Lett. 1993, 2037-2040.
(6) 121Sb and 127I Mossbauer Spectroscopic Study on Sb-I Hypervalent Bonds in Trigonal Bipyramidal Antimony (V) Complexes. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y.; Ito, Y. Hyperfine Interactions 1994, 84, 439-446.
*(7) The Wittig Rearrangement of Chiral S-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides. Kawashima, T.; Kojima, S.; Inamoto, N Bull. Chem. Soc. Jpn. 1994, 67, 2603-2606.
*(8) Characterization of an Optically Active Pentacoordinate Phosphorane with Asymmetry Only at Phosphorus. Kojima, S.; Kajiyama, K.; Akiba, K.-y. Tetrahedron Lett. 1994, 7037-7040.
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| 関連情報URL(references) | http://dx.doi.org/10.1016/S0040-4039(00)95159-1
http://dx.doi.org/10.1246/cl.1989.849
http://dx.doi.org/10.1246/cl.1992.1559
http://dx.doi.org/10.1246/cl.1992.1563
http://dx.doi.org/10.1246/cl.1993.2037
http://dx.doi.org/10.1007/BF02060694
http://dx.doi.org/10.1246/bcsj.67.2603
http://dx.doi.org/10.1016/0040-4039(94)88219-3
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| 学位記番号 | 乙第2677号
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| 授与大学 | 広島大学(Hiroshima University)
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| 学位名 | 博士(理学)
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| 学位名の英名 | Physical Science
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| 学位の種類の英名 | doctoral
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| 学位授与年月日 | 1995-03-07
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| 部局名 |
理学研究科
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