Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities
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| ID | 46212 |
| 本文ファイル | |
| 著者 |
Horiguchi, Banri
Nakaya, Toshimi
Ueda, Masafumi
大学院工学研究院
Sugikawa, Kouta
大学院工学研究科
Kawata, Naomi
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| キーワード | porphyrins
cyclodextrins
host–guest systems
molecular recognition
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| NDC |
化学
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| 抄録(英) | Porphyrin-trimethyl-β-cyclodextrin (TMe-β-CDx) complexes have pseudorotaxane structures in which two mesophenyl and/or pyridyl moieties penetrate the upper rim of two TMe-β-CDx molecules. Porphyrin derivatives with one to three pyridyl moieties at meso-positions formed complexes with TMe-β-CDx in which penetration of the upper rim of the two TMe-β-CDxs by the pyridyl moieties was minimized. In contrast, in TMe-β-CDx complexes formed with porphyrin derivatives with two 2-methoxyphenyl moieties and two pyridyl moieties, the pyridyl moieties penetrated the upper rim of the two molecules because steric hindrance prevented penetration by the 2-methoxyphenyl moieties.
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| 内容記述 | This work was supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research (B) (Grant No. JP16H04133), a Grant-in-Aid for Challenging Exploratory Research (Grant No. JP16K13982), and the Electric Technology Research Foundation of Chugoku.
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| 掲載誌名 |
European Journal of Organic Chemistry
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| 巻 | 2018巻
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| 号 | 18号
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| 開始ページ | 2138
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| 終了ページ | 2143
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| 出版年月日 | 2018-05-15
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| 出版者 | Wiley-VCH
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| ISSN | 1434-193X
1099-0690
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| 出版者DOI | |
| 言語 |
英語
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| NII資源タイプ |
学術雑誌論文
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| 広大資料タイプ |
学術雑誌論文
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| DCMIタイプ | text
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| フォーマット | application/pdf
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| 著者版フラグ | author
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| 権利情報 | Copyright (c) 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
This is the accepted version of the following article: B. Horiguchi, T. Nakaya, M. Ueda, K. Sugikawa, T. Mizuta, T. Haino, N. Kawata, A. Ikeda, Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities, Eur. J. Org. Chem., 2018, 2138–2143, which has been published in final form at http://doi.org/10.1002/ejoc.201800433. This article may be used for non-commercial purposes in accordance with Wiley Self-Archiving Policy.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
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| 部局名 |
工学研究科
理学研究科
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| 備考 | Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months.
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