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ID 40589
本文ファイル
著者
Ando, Masafumi
Kawahata, Masatoshi
Yamaguchi, Kentaro
NDC
医学
抄録(英)
Siloxy-N-silylketenimines generated in situ from Osilyl cyanohydrins were converted to α-ketoamides by brief exposure to air or oxygen. Oxidation under extremely mild conditions can be explained by assuming the intermediacy of a 3-imino-1,2-dioxetane derivative generated via triplet−singlet intersystem crossing after the reaction of siloxy-N-silylketenimines with triplet oxygen.
内容記述
This research was partially supported by a Grant-in-Aid for Scientific Research (C) 25460015 (M.S.), a Grant-in-Aid for Challenging Exploratory Research 15K14929 (K.T.) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), the Hoan Sha Foundation (M.S.), the Takeda Science Foundation (M.S.), and the Naito Foundation Natural Science Scholarship (M.S.).
掲載誌名
Organic Letters
18巻
7号
開始ページ
1598
終了ページ
1601
出版年月日
2016-04-01
出版者
American Chemical Society
ISSN
1523-7060
出版者DOI
PubMedID
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
publisher
権利情報
Copyright (c) 2016 American Chemical Society
This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
関連情報(IsVersionOf)
http://doi.org/10.1021/acs.orglett.6b00455
部局名
医歯薬保健学研究科