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ID 15053
本文ファイル
著者
Ibuki, T.
Tamenori, Y.
Takemoto, M.
Nagaoka, S.
Morishita, Y.
Suzuki, I.H.
キーワード
Angle-resolved photoelectron spectroscopy
Asymmetry parameter
Ionization energy
Valence orbital
NDC
化学
抄録(英)
Ionization energies for valence electrons of CF3SF5 were measured in the 12-35 eV region by means of angle-resolved photoelectron spectroscopy. The observed ionization energies were basically consistent with previous ones measured by threshold photoelectron and HeI photoelectron spectroscopy, and the ionization levels at 22.60, 26.92 and 27.86 eV were newly observed. Asymmetry parameter derived at hν = 684.7 eV was a constant of β = 1.02 ± 0.04 in the ionization energy lower than 20 eV, suggesting that lone pair electron of F atom is probably released through 2p → εd like electron emission. Characters of the 22 valence bands were elucidated with the help of ab initio calculations and of the nature of valence orbitals for CF4 and SF6
掲載誌名
Journal of Electron Spectroscopy and Related Phenomena
152巻
1-2号
開始ページ
96
終了ページ
99
出版年月日
2006-06
出版者
Elsevier B.V.
ISSN
0368-2048
NCID
出版者DOI
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
author
権利情報
Copyright (c) 2006 Elsevier B.V.
関連情報URL(IsVersionOf)
http://dx.doi.org/10.1016/j.elspec.2006.03.009
部局名
理学研究科