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ID 38226
本文ファイル
著者
Ohashi, Kazuhiko
Izutsu, Hironobu
Hino, Kazuyuki
Nishi, Nobuyuki
NDC
化学
抄録(英)
Vibrational and electronic spectra of the benzene–benzyl alcohol hetero-dimer ion are measured by photodissociation spectroscopy. The vibrational spectrum shows a prominent band at 3662±3 cm-1, which is assigned to the stretching vibration of the OH group free from intermolecular perturbations. The electronic spectrum shows a broad band around 950 nm, which arises from a charge resonance interaction between the aromatic rings. These results suggest that the ion has a sandwich-like structure suitable for the resonance interaction, without the hydrogen bond between the OH group of benzyl alcohol and the π-electrons of benzene.
内容記述
This work was supported in part by the Joint Studies Program (1999) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (Nos. 09740450 and 11440177) from the Ministry of Education, Science, Sports and Culture of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2000, available online: http://doi.org/10.1016/S0009-2614(00)00379-1
掲載誌名
Chemical Physics Letters
321巻
5–6号
開始ページ
406
終了ページ
410
出版年月日
2000-05-05
出版者
Elsevier B.V.
ISSN
0009-2614
出版者DOI
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
author
権利情報
(c) 2000 Elsevier Science B.V. All rights reserved.
関連情報URL(IsVersionOf)
http://doi.org/10.1016/S0009-2614(00)00379-1
部局名
理学研究科