Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities
European Journal of Organic Chemistry 2018 巻 18 号
2138-2143 頁
2018-05-15 発行
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| ファイル情報(添付) | |
| タイトル ( eng ) |
Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities
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| 作成者 |
Horiguchi Banri
Nakaya Toshimi
Kawata Naomi
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| 収録物名 |
European Journal of Organic Chemistry
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| 巻 | 2018 |
| 号 | 18 |
| 開始ページ | 2138 |
| 終了ページ | 2143 |
| 抄録 |
Porphyrin-trimethyl-β-cyclodextrin (TMe-β-CDx) complexes have pseudorotaxane structures in which two mesophenyl and/or pyridyl moieties penetrate the upper rim of two TMe-β-CDx molecules. Porphyrin derivatives with one to three pyridyl moieties at meso-positions formed complexes with TMe-β-CDx in which penetration of the upper rim of the two TMe-β-CDxs by the pyridyl moieties was minimized. In contrast, in TMe-β-CDx complexes formed with porphyrin derivatives with two 2-methoxyphenyl moieties and two pyridyl moieties, the pyridyl moieties penetrated the upper rim of the two molecules because steric hindrance prevented penetration by the 2-methoxyphenyl moieties.
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| 著者キーワード |
porphyrins
cyclodextrins
host–guest systems
molecular recognition
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| 内容記述 |
This work was supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research (B) (Grant No. JP16H04133), a Grant-in-Aid for Challenging Exploratory Research (Grant No. JP16K13982), and the Electric Technology Research Foundation of Chugoku.
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| NDC分類 |
化学 [ 430 ]
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| 言語 |
英語
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| 資源タイプ | 学術雑誌論文 |
| 出版者 |
Wiley-VCH
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| 発行日 | 2018-05-15 |
| 権利情報 |
Copyright (c) 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
This is the accepted version of the following article: B. Horiguchi, T. Nakaya, M. Ueda, K. Sugikawa, T. Mizuta, T. Haino, N. Kawata, A. Ikeda, Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities, Eur. J. Org. Chem., 2018, 2138–2143, which has been published in final form at http://doi.org/10.1002/ejoc.201800433. This article may be used for non-commercial purposes in accordance with Wiley Self-Archiving Policy.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
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| 出版タイプ | Author’s Original（十分な品質であるとして、著者から正式な査読に提出される版） |
| アクセス権 | オープンアクセス |
| 収録物識別子 |
[ISSN] 1434-193X
[ISSN] 1099-0690
[DOI] 10.1002/ejoc.201800433
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| 備考 | Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months. |
