Vibrational and electronic spectra of (benzene-benzyl alcohol)+. Predominance of charge resonance interaction over hydrogen bonding interaction

Chemical Physics Letters 321 巻 5–6 号 406-410 頁 2000-05-05 発行
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タイトル ( eng )
Vibrational and electronic spectra of (benzene-benzyl alcohol)+. Predominance of charge resonance interaction over hydrogen bonding interaction
作成者
Ohashi Kazuhiko
Izutsu Hironobu
Hino Kazuyuki
Nishi Nobuyuki
収録物名
Chemical Physics Letters
321
5–6
開始ページ 406
終了ページ 410
抄録
Vibrational and electronic spectra of the benzene–benzyl alcohol hetero-dimer ion are measured by photodissociation spectroscopy. The vibrational spectrum shows a prominent band at 3662±3 cm-1, which is assigned to the stretching vibration of the OH group free from intermolecular perturbations. The electronic spectrum shows a broad band around 950 nm, which arises from a charge resonance interaction between the aromatic rings. These results suggest that the ion has a sandwich-like structure suitable for the resonance interaction, without the hydrogen bond between the OH group of benzyl alcohol and the π-electrons of benzene.
内容記述
This work was supported in part by the Joint Studies Program (1999) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (Nos. 09740450 and 11440177) from the Ministry of Education, Science, Sports and Culture of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2000, available online: http://doi.org/10.1016/S0009-2614(00)00379-1
NDC分類
化学 [ 430 ]
言語
英語
資源タイプ 学術雑誌論文
出版者
Elsevier B.V.
発行日 2000-05-05
権利情報
(c) 2000 Elsevier Science B.V. All rights reserved.
出版タイプ Author’s Original(十分な品質であるとして、著者から正式な査読に提出される版)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 0009-2614
[DOI] 10.1016/S0009-2614(00)00379-1
[DOI] http://doi.org/10.1016/S0009-2614(00)00379-1 ~の異版である