Stereochemistry and Reactions of Pentacoordinate Organophosphorus Compounds with Martin Ligands
Use this link to cite this item : http://doi.org/10.11501/3131312
| ID | 31888 |
| file | |
| title alternative | マーチンリガンドを有する5配位有機リン化合物の立体化学と反応
|
| creator |
Kajiyama, Kazumasa
|
| NDC |
Chemistry
|
| contents | Contents
Chapter 1.General Introduction A.General Introduction / p1 B.References / p12 Chapter 2.Syntheses and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H(Apical) Phosphoranes Bearing a Hydroxy Group. A.Introduction / p16 B.Results and Discussion / p18 C.Experimental Section / p38 D.References / p55 Chapter 3.First Characterization of 10-P-5 Spirophosphoranes with an Apical Carbon-Equatorial Oxygen ring. Kinetic Studies on Pseudorotation. A.Introduction / p57 B.Results and Discussion / p60 C.Experimental Section / p75 D.References / p99 Chapter 4.Kinetic Studies of Thermal Cyclization Reactions of P-H(apical) Phosphoranes Bearing a Hydroxy Group. A.Introduction / p101 B.Results and Discussion / p104 C.Experimental Section / p115 D.References / p136 Acknowledgements / p138 List of Publications / p139 |
| SelfDOI | |
| language |
eng
|
| nii type |
Thesis or Dissertation
|
| HU type |
Doctoral Theses
|
| DCMI type | text
|
| format | application/pdf
|
| text version | ETD
|
| rights | Copyright(c) by Author
|
| relation references | *(4) Synthesis and Characterization of Intra- and Intermolecular Hydrogen Bonding Isomers of P-H (apical) Phosphoranes Bearing a Hydroxyl Group and Their Thermal Cyclization. Kajiyama, K.; Kojima, S.; Akiba, K.-y. Tetrahedron Lett. 1996, 37, 8409-8412.
*(5) First Characterization of a 10-P-5 Spirophosphorane with an Apical Carbon-Equatorial Oxygen Ring. Kinetic Studies on Pseudorotation of Stereoisomers. Kojima, S.; Kajiyama, K.; Nakamoto, M.; Akiba, K.-y. J. A in. Chem. Soc. 1996, 118, 12866-12867.
|
| relation references URL | http://dx.doi.org/10.1016/0040-4039(96)01923-5
http://dx.doi.org/10.1021/ja9621408
|
| grantid | 甲第1583号
|
| degreeGrantor | 広島大学(Hiroshima University)
|
| degreename Ja | 博士(理学)
|
| degreename En | Physical Science
|
| degreelevel | doctoral
|
| date of granted | 1997-03-25
|
| department |
Graduate School of Science
|
