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ID 16632
file
creator
Kubo, Akira
Kini, N. S.
Inoue, Toru
Irifune, Tetsuo
NDC
Physics
abstract
Single crystals of three-dimensional (3D) C60 polymer were prepared by the topotactic conversion of two-dimensional (2D) C60 polymer single crystals at a pressure of 15 GPa at 600°C. The x-ray single crystal study revealed that the 3D C60 polymer crystallized in a body centered orthorhombic space group Immm, and spherical C60 monomer units were substantially deformed to rectangular parallelepiped (cuboidal) shapes, each unit being bonded to eight cuboidal C60 neighbors via [3+3] cycloaddition. The 3D C60 polymer was electron conductive, in contrast with the nonconductive behavior of 2D polymers.
journal title
Physical Review Letters
volume
Volume 96
issue
Issue 7
start page
076602
date of issued
2006
publisher
American Physical Society
issn
0031-9007
ncid
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
publisher
rights
Copyright (c) 2006 American Physical Society
relation url
department
Graduate School of Engineering