このエントリーをはてなブックマークに追加
ID 40589
file
creator
Ando, Masafumi
Kawahata, Masatoshi
Yamaguchi, Kentaro
NDC
Medical sciences
abstract
Siloxy-N-silylketenimines generated in situ from Osilyl cyanohydrins were converted to α-ketoamides by brief exposure to air or oxygen. Oxidation under extremely mild conditions can be explained by assuming the intermediacy of a 3-imino-1,2-dioxetane derivative generated via triplet−singlet intersystem crossing after the reaction of siloxy-N-silylketenimines with triplet oxygen.
description
This research was partially supported by a Grant-in-Aid for Scientific Research (C) 25460015 (M.S.), a Grant-in-Aid for Challenging Exploratory Research 15K14929 (K.T.) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), the Hoan Sha Foundation (M.S.), the Takeda Science Foundation (M.S.), and the Naito Foundation Natural Science Scholarship (M.S.).
journal title
Organic Letters
volume
Volume 18
issue
Issue 7
start page
1598
end page
1601
date of issued
2016-04-01
publisher
American Chemical Society
issn
1523-7060
publisher doi
pubmed id
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
publisher
rights
Copyright (c) 2016 American Chemical Society
This is an open access article published under an ACS AuthorChoice License, which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
relation is version of
http://doi.org/10.1021/acs.orglett.6b00455
department
Graduate School of Biomedical & Health Sciences