Fermi resonance interaction in hetero-dimer and trimer ions containing aniline+
Use this link to cite this item : https://ir.lib.hiroshima-u.ac.jp/00014703
ID | 14703 |
file | |
creator |
Ohshimo, Keijiro
Ohashi, Kazuhiko
Honkawa, Yoshiki
Nishi, Nobuyuki
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NDC |
Chemistry
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abstract | Vibrational spectra of hetero-dimer and trimer ions containing aniline+ are measured by infrared photodissociation spectroscopy. For the dimer ions, the NH2-bending overtone band gains its intensity through Fermi resonance interaction with the hydrogen-bonded NH stretching fundamental. Unperturbed frequencies of the NH2-bending overtone are calculated to be in the range of 3255-3276 cm-1, suggesting that the frequency is almost intact upon cluster formation. For the trimer ions, Fermi resonance interaction occurs mainly between the NH2-bending overtone and the stretching fundamental of the NH oscillator involved in the stronger hydrogen bond.
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journal title |
Chemical Physics Letters
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volume | Volume 373
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issue | Issue 5-6
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start page | 568
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end page | 574
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date of issued | 2003-05
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publisher | Elsevier B. V.
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issn | 0009-2614
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language |
eng
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nii type |
Journal Article
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HU type |
Journal Articles
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DCMI type | text
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format | application/pdf
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text version | author
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rights | Copyright (c) 2003 Elsevier B. V.
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relation is version of URL | http://dx.doi.org/10.1016/S0009-2614(03)00647-X
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department |
Graduate School of Science
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