Electronic and vibrational spectra of aniline―benzene heterodimer and aniline homo-dimer ions
Use this link to cite this item : https://ir.lib.hiroshima-u.ac.jp/00037373
ID | 37373 |
file | |
creator |
Ohashi, Kazuhiko
Izutsu, Hironobu
Hino, Kazuyuki
Yamamoto, Norifumi
Nishi, Nobuyuki
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NDC |
Chemistry
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abstract | Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.
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journal title |
Chemical Physics Letters
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volume | Volume 323
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issue | Issue 1-2
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start page | 43
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end page | 48
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date of issued | 2000-06
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publisher | Elsevier B.V.
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issn | 0009-2614
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publisher doi | |
language |
eng
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nii type |
Journal Article
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HU type |
Journal Articles
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DCMI type | text
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format | application/pdf
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text version | author
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rights | Copyright (c) 2000 Elsevier Science B.V.
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relation is version of URL | http://dx.doi.org/10.1016/S0009-2614(00)00497-8
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department |
Graduate School of Science
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