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Unsymmetrical B(MIDA)-containing diborons of potential synthetic utility were found to be synthesized from the readily available (neop)B–B(neop) and (HO)2B–B(OH)2, and the procedure was extended to the generation of symmetrical (MIDA)B–B(MIDA). NMR and X-ray crystal structure studies revealed that B(MIDA) units of all of the diborons obtained in this study were in rigid tetrahedral environment.
This work was financially supported by JSPS KAKENHI Grant Numbers JP16H01031 in Precisely Designed Catalysts with Customized Scaffolding and JP17K05864.
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American Chemical Society
This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Omega, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acsomega.7b01042.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
Graduate School of Engineering
Graduate School of Science