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ID 49752
file
creator
Kato, Chisato
Machida, Ryo
Maruyama, Rio
Tsunashima, Ryo
Ren, Xiao-Ming
Kurmoo, Mohamedally
subject
molecular devices
molecular electronics
polyoxometalates
terbium
abstract
Continual progress has been achieved in information technology through unrelenting miniaturisation of the single memory bit in integrated ferromagnetic, ferroelectric, optical, and related circuits. However, as miniaturisation approaches its theoretical limit, new memory materials are being sought. Herein, we report a unique material exhibiting single‐molecule electric polarisation switching that can operate above room temperature. The phenomenon occurs in a Preyssler‐type polyoxometalate (POM) cluster we call a single‐molecule electret (SME). It exhibits all the characteristics of ferroelectricity but without long‐range dipole ordering. The SME affords bi‐stability as a result of the two potential positions of localisation of a Tb3+ ion trapped in the POM, resulting in extremely slow relaxation of the polarisation and electric hysteresis with high spontaneous polarisation and coercive electric fields. Our findings suggest that SMEs can potentially be applied to ultrahigh‐density memory and other molecular‐level electronic devices operating above room temperature.
description
This study was supported by JSPS KAKENHI Grant Numbers JP16H04223, JP16K14101, JP24350095, and JP25220803;the Joint Research Project between JSPS and the National Science Foundation of China (NSFC);and JSPS Core-to-Core Program, A. Advanced Research Networks. This work was also performed under the aegis of the Canon Science Promotion Foundation, Murata Science Foundation, Casio Science Promotion Foundation, and the Cooperative Research Program of “Network Joint Research Centre for Materials and Devices”. M.K. is also funded by CNRS, France.
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journal title
Angewandte Chemie International Edition
volume
Volume 57
issue
Issue 41
start page
13429
end page
13432
date of issued
2018-10-08
publisher
Wiley
issn
1433-7851
1521-3773
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
This is the peer reviewed version of the following article: C. Kato, R. Machida, R. Maruyama, R. Tsunashima, X.-M. Ren, M. Kurmoo, K. Inoue, S. Nishihara, Angew. Chem. Int. Ed. 2018, 57, 13429., which has been published in final form at https://doi.org/10.1002/anie.201806803. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
This is not the published version. Please cite only the published version. この論文は出版社版ではありません。引用の際には出版社版をご確認、ご利用ください。
relation is version of URL
https://doi.org/10.1002/anie.201806803
department
Graduate School of Science



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