Reversible Supramolecular System of Porphyrin Exchange between Inclusion in Cyclodextrin and Intercalation in DNA by Change in pH
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Under the coexistence of cyclodextrin and DNA in water, 5,10,15,20-tetra(4-pyridyl)porphyrin interacted with the cavities of two cyclodextrin molecules in a solution at an around neutral pH and intercalated into DNA under acidic conditions. The supramolecular phenomena occurred completely and reversibly owing to the change in pH.
This work was supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research (B) (Grant No. JP16H04133) and a Grant-in-Aid for Challenging Exploratory Research (Grant No. JP16K13982).
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This is the accepted version of the following article: S. Notsu, K. Sugikawa, A. Ikeda, Reversible Supramolecular System of Porphyrin Exchange between Inclusion in Cyclodextrin and Intercalation in DNA by Change in pH, ChemistrySelect, 3, 5900–5904, 2018, which has been published in final form at http://doi.org/10.1002/slct.201801070. This article may be used for non-commercial purposes in accordance with Wiley Self-Archiving Policy.
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認ご利用ください。
Graduate School of Engineering
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