Electronic Structures of Aromatic Cluster Ions
Use this link to cite this item : https://ir.lib.hiroshima-u.ac.jp/00038470
ID | 38470 |
file | |
creator |
Ohashi, Kazuhiko
Nakai, Yasuhiro
Shibata, Takeshi
Nishi, Nobuyuki
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NDC |
Chemistry
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abstract | The photodissociation spectra are observed for cluster ions of several aromatic molecules including benzene, toluene, and phenol. Benzene cluster ions, (C6H6)n+ with n = 3-6, retain spectroscopic features characteristic of (C6H6)2+, suggesting that the positive charge is carried by a dimer subunit in (C6H6)n+. The spectrum of (benzene-toluene)+ shows charge resonance bands, which are commonly seen in homo-dimer ions. The resonance interaction is also important in the hetero-dimer ion, despite the difference in the ionization potentials between the two components. Phenol dimer ion exhibits no strong charge resonance band, although it is a homo-dimer ion. Owing to the geometrical constraint of an O-H・・・O hydrogen bond, the two aromatic rings cannot be in a parallel configuration suitable for the resonance interaction.
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journal title |
Proceedings of the Yamada Conference XLIII on Structures and Dynamics of Clusters : May 10-13, 1995, Shimoda, Shizuoka, Japan
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start page | 357
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end page | 362
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date of issued | 1996
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publisher | Universal Academy Press
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contributor | Yamada Science Foundation
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isbn | 4946443304
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language |
eng
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nii type |
Book
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HU type |
Book Chapters
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DCMI type | text
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format | application/pdf
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text version | publisher
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rights | Copyright (c) 1996 by Universal Academy Press, Inc. and Yamada Science Foundation
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department |
Graduate School of Science
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