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ID 38226
file
creator
Ohashi, Kazuhiko
Izutsu, Hironobu
Hino, Kazuyuki
Nishi, Nobuyuki
NDC
Chemistry
abstract
Vibrational and electronic spectra of the benzene–benzyl alcohol hetero-dimer ion are measured by photodissociation spectroscopy. The vibrational spectrum shows a prominent band at 3662±3 cm-1, which is assigned to the stretching vibration of the OH group free from intermolecular perturbations. The electronic spectrum shows a broad band around 950 nm, which arises from a charge resonance interaction between the aromatic rings. These results suggest that the ion has a sandwich-like structure suitable for the resonance interaction, without the hydrogen bond between the OH group of benzyl alcohol and the π-electrons of benzene.
description
This work was supported in part by the Joint Studies Program (1999) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (Nos. 09740450 and 11440177) from the Ministry of Education, Science, Sports and Culture of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2000, available online: http://doi.org/10.1016/S0009-2614(00)00379-1
journal title
Chemical Physics Letters
volume
Volume 321
issue
Issue 5–6
start page
406
end page
410
date of issued
2000-05-05
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
(c) 2000 Elsevier Science B.V. All rights reserved.
relation is version of URL
http://doi.org/10.1016/S0009-2614(00)00379-1
department
Graduate School of Science



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