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ID 38224
file
creator
Ohashi, Kazuhiko
Nishiguchi, Masaharu
Nishi, Nobuyuki
NDC
Chemistry
abstract
Electronic spectra of a homo-molecular dimer cation, (C6H5CN)2+, are measured by photodissociation spectroscopy in the gas phase. Broad features appeared in the 450–650 nm region are characteristic of π3 → πCN transitions of the C6H5CN+ chromophore. No intense band is observed in the 650–1300 nm region, where other aromatic dimer cations usually show charge resonance bands. Two component molecules of (C6H5CN)2+ cannot take a parallel sandwich configuration suitable for the resonance interaction, because of geometrical constraints due to other stronger interactions.
description
This work was supported in part by a Grant-in-Aid for Scientific Research (No. 09740450) from the Ministry of Education, Science, Sports and Culture of Japan.
This is a postprint of an article published by Springer Netherlands in Research on Chemical Intermediates, 1998, available online: http://doi.org/10.1163/156856798X00393
journal title
Research on Chemical Intermediates
volume
Volume 24
issue
Issue 7
start page
755
end page
764
date of issued
1998-07
publisher
Springer Netherlands
issn
0922-6168
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
(c) VSP 1998
relation is version of
http://doi.org/10.1163/156856798X00393
department
Graduate School of Science



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