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ID 37652
file
creator
Doi, Keisuke
Togano, Eijiro
Xantheas, Sotiris S.
Nakanishi, Ryuzo
Nagata, Takashi
subject
halides
IR spectroscopy
SN2 reactions
solvent effects
NDC
Chemistry
abstract
Hydrated I-(CH3I) complexes, I-(CH3I)(H2O)1-3, are investigated by IR photodissociation spectroscopy for examining the stable structures of the intermediates of the (I- + CH3I → ICH3 + I-) SN2 reaction under hydrated conditions. The structures and the energetics of the complexes suggest that just one or two H2O molecules will effectively inhibit this SN2 reaction.
journal title
Angewandte Chemie International Edition
volume
Volume 52
issue
Issue 16
start page
4380
end page
4383
date of issued
2013-01-30
publisher
Wiley-VCH Verlag GmbH
issn
1521-3773
ncid
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
relation is version of
http://doi.org/10.1002/anie.201207697
department
Graduate School of Science



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