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ID 14690
file
creator
Ohshimo, Keijiro
Misaizu, Fuminori
Nishi, Nobuyuki
NDC
Chemistry
abstract
Infrared spectra of [Mg·(H2O)1,2]+ and [Al·(H2O)1,2]+ are measured in the OH stretching region (3200-3800 cm-1). The spectra show the symmetric and asymmetric OH stretching bands of water molecules that are directly bound to the metal ions through metal-oxygen intermolecular bonds. In addition to these bands, the [Al·(H2O)2]+ ion has another band at 3714 cm-1. This band is assigned to the free OH stretching vibration of the [HO-Al-H]+ ion; the aluminum ion is inserted into the O-H bond of one water molecule in [Al·(H 2O)2]+.
journal title
Chemical Physics Letters
volume
Volume 390
issue
Issue 1-3
start page
140
end page
144
date of issued
2004-05
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2004 Elsevier B.V.
relation is version of URL
http://dx.doi.org/10.1016/j.cplett.2004.03.148
department
Graduate School of Science



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