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ID 182
file
creator
Sumi, Koichi
Hagisawa, Susumu
subject
Inter-element linkage
Silyl thioketone
Thia-Brook rearrangement
Sulfur-phosphorus bond
sulfur-silicon bond
NDC
Chemistry
abstract
Reaction of silyl thioketone 7 with lithium diethylphosphite at –98 °C afforded an S-attack product 8 and a formal C-attack products 10 and 11, which were formed by S-to-C migration of the phosphoryl group in 8 followed by C-to-S migration of the silyl group (thia-Brook rearrangemnet), in a ratio depending on the conditions. The relative facility of the thia-Brook rearrangement was compared with that of the Brook rearrangement using the (t-butyldimethylsilyl) diphenylmethyl derivatives 22 and 23.
journal title
Journal of organometallic chemistry
volume
Volume 611
issue
Issue 1-2
start page
449
end page
454
date of issued
2000-10-06
publisher
Elsevier Science
issn
0022-328X
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2000 Elsevier Science S.A.
relation is version of URL
http://dx.doi.org/10.1016/S0022-328X(00)00482-4
department
Graduate School of Biomedical Science



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