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ID 36739
本文ファイル
著者
Itoh, Keiji
Fukunaga, Toshiharu
Fuji, Hironobu
NDC
化学
抄録(英)
The nanostructural hydrogenated graphite (CnanoHx) was synthesized from graphite by ball milling under hydrogen (H2) atmosphere. In this product, characteristic hydrogenated states in the form of polarized hydrocarbon groups (―CH, ―CH2, and ―CH3) are realized in the nanoscale. By synthesizing the composite of CnanoHx and lithium hydride (LiH), known as the Li―C―H system, hydrogen was desorbed at 350 °C, which is a lower temperature compared to the decomposition temperature of each component. It is considered that this hydrogen desorption would be induced by destabilization of each hydrogen absorbed state due to an interaction between the polarized C―H groups in CnanoHx and LiH. Therefore, in order to understand the hydrogen absorption/desorption mechanism of the Li―C―H system, it is an important issue to investigate the change in the C―H groups during hydrogen absorption/desorption reactions in the composite. The correlations among atoms contained in this composite are examined by neutron diffraction measurements, where the protium/deuterium (H/D) isotopic substitution was used to clarify the location of hydrogen atoms in this composite. Some C―D and Li―D correlations are found from the radial distribution function [RDF(r)] obtained by the neutron diffraction for the CnanoDx and LiD composite. After dehydrogenation, C―C triple bond and Li―C bond, ascribed to lithium carbide (Li2C2), are observed. Furthermore, the RDF(r) corresponding to rehydrogenated composite indicates the presence of not only the Li―D correlation but also the C―D one.
掲載誌名
Journal of Applied Physics
104巻
5号
開始ページ
053511
出版年月日
2008-09
出版者
American Institute of Physics
ISSN
0021-8979
NCID
出版者DOI
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
publisher
権利情報
Copyright 2008 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in J. Appl. Phys. 104, 053511 and may be found at http://dx.doi.org/10.1063/1.2956504.
関連情報URL
部局名
先端物質科学研究科
先進機能物質研究センター