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ID 38231
本文ファイル
著者
Ohashi, Kazuhiko
Terabaru, Kazutaka
Mune, Yutaka
Machinaga, Hironobu
Nishi, Nobuyuki
NDC
化学
抄録(英)
The infrared photodissociation spectra of mass-selected Mg+(NH3)n (n = 3–6) are measured and analyzed with the aid of density functional theory calculations. No large frequency reduction is observed for the NH stretches of ammonia, suggesting that either all the ammonia molecules coordinate directly to the Mg+ ion or an additional ammonia in the second shell bridges two ammonias in the first shell through hydrogen bonds. Four or possibly five ammonia molecules are allowed to occupy the first shell, in striking contrast to the closure of the first shell in Mg+(H2O)3.
内容記述
This work was supported in part by the Joint Studies Program (2003) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 15250015) from the Ministry of Education, Culture, Sports, Science, and Technology of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2004, available online: http://doi.org/10.1016/j.cplett.2004.06.048
掲載誌名
Chemical Physics Letters
393巻
1–3号
開始ページ
264
終了ページ
270
出版年月日
2004-07-21
出版者
Elsevier B.V.
ISSN
0009-2614
出版者DOI
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
author
権利情報
(c) 2004 Elsevier B.V. All rights reserved.
関連情報URL(IsVersionOf)
http://doi.org/10.1016/j.cplett.2004.06.048
部局名
理学研究科