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ID 38228
本文ファイル
著者
Ohashi, Kazuhiko
Nishi, Nobuyuki
NDC
化学
抄録(英)
The charge distribution and binding features of aniline/benzene hetero-trimer and aniline homo-trimer ions are investigated by vibrational spectroscopy and by near-infrared photodissociation and spontaneous unimolecular dissociation of mass-selected cluster ions. The absence of the charge resonance absorption indicates the charge localization in the trimer ions. Substantial red-shifts and enhanced intensities of the vibrational transitions suggest strong perturbations to the NH oscillators. The trimer ions are stabilized by the hydrogen-bonding interaction through the NH2 group of the charged aniline with the neutral molecules rather than the charge-delocalization interaction among the component molecules.
内容記述
This work was supported in part by the Joint Studies Program (2001) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 11440177) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2002, available online: http://doi.org/10.1016/S0009-2614(02)00490-6
掲載誌名
Chemical Physics Letters
357巻
3–4号
開始ページ
223
終了ページ
229
出版年月日
2002-05-10
出版者
Elsevier B.V.
ISSN
0009-2614
出版者DOI
言語
英語
NII資源タイプ
学術雑誌論文
広大資料タイプ
学術雑誌論文
DCMIタイプ
text
フォーマット
application/pdf
著者版フラグ
author
権利情報
(c) 2002 Elsevier Science B.V. All rights reserved.
関連情報(IsVersionOf)
http://doi.org/10.1016/S0009-2614(02)00490-6
部局名
理学研究科