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ID 48221
creator
Tanaka, Hideya
Kuriki, Hitoshi
Kubo, Teruhiko
abstract
Copper-catalyzed arylstannylation of arynes has been developed. This transformation enables variously substituted ortho-stannylbiaryls and teraryls to be constructed straightforwardly. An electron-deficient tin center is the key, and thus the single or dual insertion of arynes into arylstannanes is precisely controllable by simply changing the equivalence of aryne precursors.
description
This work was financially supported by JSPS KAKENHI Grant Number JP17K05864.
journal title
Chemical Communications
volume
Volume 55
issue
Issue 46
start page
6503
end page
6506
date of issued
2019-06-11
publisher
Royal Society of Chemistry
issn
1359-7345
1364-548X
publisher doi
pubmed id
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
© The Royal Society of Chemistry 2019
This is not the published version. Please cite only the published version. この論文は出版社版でありません。引用の際には出版社版をご確認、ご利用ください。
relation
Electronic supplementary information (ESI) available: Experimental procedures and characterization data. See DOI: 10.1039/c9cc02738f
department
Graduate School of Engineering
note
Post-print version/PDF may be used in an institutional repository after an embargo period of 12 months.