ID 31858
file
title alternative
4配位および5配位有機リンおよびアンチモン化合物の立体化学
creator
NDC
Chemistry
contents
Contents
General Introduction / p1
References / p18
Chapter1.Preparation of Optically Active Phosphine Oxides via Wittig Type Rearrangement and Phosphine Sulfides via Alkylation of Lithium Phosphinothioites.
 1.Introduction / p21
 2.Results and Discussion / p25
 3.Experimental / p50
 4.References / p70
Chapter2.Characterization of the FirstEnantiomericPairs of Stereochemically Definable Hypervalent 10-P-5 Phosphoranes with Asymmetry Only at Phosphorus.
 1.Introduction / p72
 2.Results and Discussion / p74
 3.Experimental / p97
 4.References / p108
Chapter3.The First Stereochemical Characterization of Configurationally Stable Diastereomers of Hypervalent 10-Sb-5 Stiboranes and Acceleration of Intramolecular Permutation by Donor Solvents
 1.Introduction / p110
 2.Results and Discussion / p112
 3.Experimental / p137
 4.References / p142
List of Publications / p145
SelfDOI
language
eng
nii type
Thesis or Dissertation
HU type
Doctoral Theses
DCMI type
text
format
application/pdf
text version
ETD
rights
Copyright(c) by Author
relation references
*(1) The Wittig Rearrangement of Chiral Phosphinothioates Induced by the Tin-Lithium Transmetallation. Kawashima, T.; Kojima, S.; Miyake, T.; Inamoto, N. Tetrahedron Lett. 1989, 201-204.
*(2) The Optically Active Phosphinodithioates. Synthesis and Conversion to Optically Active Phosphine Sulfides. Kawashima, T.; Kojima, S.; Inamoto, N. Chem. Lett. 1989, 849-852.
*(3) Synthesis, Structure, and Reactions of a 10-Sb-4 Type Antimony Ate Complex. Akiba, K.-y.; Nakata, H.; Yamamoto, Y.; Kojima, S. Chem. Lett. 1992, 1559-1562.
(4) Synthesis, Structure, and Reactions of 10-Sn-5 Organotin Ate Complexes. Akiba, K.-y. ; Ito, Y.; Kondo, F.; Ohashi, N.; Sakaguchi, A.; Kojima, S.; Yamamoto, Y. Chem. Lett. 1992, 1562-1566.
(5) 121Sb Mossbauer Spectra of Hexafluorocumyl Alcohol Complexes of Sb(V) and of Sb(III) with Negative Quadrupole Coupling Constants. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y. Chem. Lett. 1993, 2037-2040.
(6) 121Sb and 127I Mossbauer Spectroscopic Study on Sb-I Hypervalent Bonds in Trigonal Bipyramidal Antimony (V) Complexes. Takeda, M.; Takahashi, M.; Yanagida, Y.; Kojima, S.; Akiba, K.-y.; Ito, Y. Hyperfine Interactions 1994, 84, 439-446.
*(7) The Wittig Rearrangement of Chiral S-Methyl Phosphinothioates Promoted by Direct Deprotonation with Lithium Dialkylamides. Kawashima, T.; Kojima, S.; Inamoto, N Bull. Chem. Soc. Jpn. 1994, 67, 2603-2606.
*(8) Characterization of an Optically Active Pentacoordinate Phosphorane with Asymmetry Only at Phosphorus. Kojima, S.; Kajiyama, K.; Akiba, K.-y. Tetrahedron Lett. 1994, 7037-7040.
relation references URL
http://dx.doi.org/10.1016/S0040-4039(00)95159-1
http://dx.doi.org/10.1246/cl.1989.849
http://dx.doi.org/10.1246/cl.1992.1559
http://dx.doi.org/10.1246/cl.1992.1563
http://dx.doi.org/10.1246/cl.1993.2037
http://dx.doi.org/10.1007/BF02060694
http://dx.doi.org/10.1246/bcsj.67.2603
http://dx.doi.org/10.1016/0040-4039(94)88219-3
grantid
乙第2677号
degreeGrantor
広島大学(Hiroshima University)
degreename Ja
博士(理学)
degreename En
Physical Science
degreelevel
doctoral
date of granted
1995-03-07
department
Graduate School of Science