ID 31887
file
title alternative
新規でカチオニックなジエーテルを配位子とするルイス酸を用いた不斉合成とピペリドンおよび1,2-アミノアルコールの立体選択的合成
creator
Ishimaru, Kaori
NDC
Chemistry
contents
CONTENTS
Chapter 1.Asymmetric Synthesis Using Novel Cationic Diether-Coordinated Lewis Acids
 1-1.Introduction / p1
 1-2.Cationic Lewis Acids for [4+2]Type Cycloaddition of α-Chiral Aldimines / p12
 1-3.Development of Novel Cationic Lewis Acids Coordinated by a Chiral Diether Ligand / p18
 1-4.Attempt to Develop Novel Lewis Acids Bearinga Monoether-Coordinated Ligand / p31
 1-5.Aldol Reaction by Using the Novel Cationic Lewis Acids / p39
 1-6.Synthesis of the Modified Chiral Ligands / p44
 1-7.Structure of Chiral Diether-Coordinated Titanium Complexes / p47
 1-8.Summary / p51
 1-9.Experimental Section / p52
 1-10.References / p74
Chapter 2.Stereocontrol in [4+2]Type Cycloaddition of Imines Bearing α-Hydrogens with 2-Silyloxy-l,3-butadienes
 2-1.Introduction / p77
 2-2.[4+2]Type Cycloaddition of Imines bearing a-Hydrogens / p82
 2-3.[4+2]Type Cycloaddition of ct-Silyloxyimines / p84
 2-4.Summary / p98
 2-5.Experimental Section / p99
 2-6.References / p122
Chapter 3.Stereoselective Synthesis of 1,2-Amino Alcohols by Nucleophilic Addition of Organometallic Reagents to α-Silyloxyimines
 3-1.Introduction / p124
 3-2.Nucleophilic Addition of Organometallic Reagents to an α-Silyloxyimines / p131
 3-3.Summary / p138
 3-4.Experimental Section / p139
 3-5.References / p150
SelfDOI
language
eng
nii type
Thesis or Dissertation
HU type
Doctoral Theses
DCMI type
text
format
application/pdf
text version
ETD
rights
Copyright(c) by Author
relation references
1* Kin-ya Akiba, Toshihiro Motoshima, Kaori Ishimaru, Kazutaka Watanabe, Hiroshi Hirota and Yohsuke Yamamoto. [4+2]Type Cycloaddition of Aldimines Bearing α-Hydrogens with 2-Silyloxy-1,3-butadienes Catalyzed by Trimethylsilyl Triflate, Synlett, 1993, 657-659.
2* Kaori Ishimaru, Kazutaka Watanabe, Yohsuke Yamamoto and Kin-ya Akiba. Stereocontrol in [4+2]Type Cycloaddition of an Aldimine Derived from (S)-Ethyl Lactate with 2-Silyloxy-1,3-butadienes, Synlett, 1994, 495-498.
3* Kaori Ishimaru, Kazutaka Tsuru, Katsunori Yabuta, Makoto Wada, Yohsuke Yamamoto and Kin-ya Akiba. Stereoselective Synthesis of 1,2-Amino Alcohols by Addition of Organocuprate• BF3 Complexes and Organolithium Reagents to an α-Silyloxyaldimine Derived from (S)-Ethyl Lactate, Tetrahedron, 1996, 52, 13137-13144.
relation references URL
http://dx.doi.org/10.1016/0040-4020(96)00776-4
grantid
甲第1582号
degreeGrantor
広島大学(Hiroshima University)
degreename Ja
博士(理学)
degreename En
Physical Science
degreelevel
doctoral
date of granted
1997-03-25
department
Graduate School of Science