このエントリーをはてなブックマークに追加
ID 37381
file
creator
Machinaga, Hironobu
Ohashi, Kazuhiko
Nishi, Nobuyuki
NDC
Chemistry
abstract
The infrared photodissociation spectra of mass-selected Mg+(CH3OH)n (n=1–4) are measured and analyzed with the aid of density functional theory calculations. Hydrogen bonding between methanol molecules is found to be absent in Mg+(CH3OH)3, but detected in Mg+(CH3OH)4 through characteristic frequency shifts of the OH stretch of methanol. The maximum number of the methanol molecules that can be directly bonded to the Mg+ ion is limited to three and the fourth molecule starts to fill the second solvation shell. The vibrational spectroscopy provides clear evidence for the closure of the first shell at n=3.

journal title
Chemical Physics Letters
volume
Volume 391
issue
Issue 1-3
start page
85
end page
90
date of issued
2004-06
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2004 Published by Elsevier B.V.
relation is version of URL
http://dx.doi.org/10.1016/j.cplett.2004.04.094
department
Graduate School of Science