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ID 37373
file
creator
Ohashi, Kazuhiko
Izutsu, Hironobu
Hino, Kazuyuki
Yamamoto, Norifumi
Nishi, Nobuyuki
NDC
Chemistry
abstract
Structures of (aniline-benzene)+ and (aniline)2+ are re-investigated by electronic spectroscopy in the near-infrared region and vibrational spectroscopy in the NH stretching region. The spectra of (aniline-benzene)+ indicate a structure including a hydrogen bond between an NH bond of the ionic aniline and the π-electrons of the neutral benzene. Two isomers are suggested for (aniline)2+ in which an NH bond of the ionic aniline forms different types of hydrogen bond with the neutral aniline: one with the π-electrons of the aromatic ring and the other with the lone pair of the nitrogen atom.
journal title
Chemical Physics Letters
volume
Volume 323
issue
Issue 1-2
start page
43
end page
48
date of issued
2000-06
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2000 Elsevier Science B.V.
relation is version of URL
http://dx.doi.org/10.1016/S0009-2614(00)00497-8
department
Graduate School of Science