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ID 38229
file
creator
Honkawa, Yoshiki
Ohashi, Kazuhiko
Nishi, Nobuyuki
NDC
Chemistry
abstract
Infrared photodissociation spectra of the aniline ion solvated by water and methanol molecules are measured in the 2600–3800 cm-1 region. Substantially red-shifted and broadened transitions are distinctly observed at 3105 and 2915 cm-1 for aniline+-(H2O)1 and aniline+-(CH3OH)1, respectively, and assigned to the stretching vibration of the hydrogen-bonded NH oscillator of the aniline+ moiety. The spectra of aniline+-(H2O)2 and aniline+-(CH3OH)2 demonstrate a large perturbation to both of the NH oscillators, indicating that each NH bond is bound to a solvent molecule in the most stable structure.
description
This work was supported in part by the Joint Studies Program (2001) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 11440177) from the Ministry of Education, Culture, Sports, Science and Technology of Japan.
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2002, available online: http://doi.org/10.1016/S0009-2614(02)00641-3
journal title
Chemical Physics Letters
volume
Volume 358
issue
Issue 5–6
start page
419
end page
425
date of issued
2002-06-07
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
(c) 2002 Elsevier Science B.V. All rights reserved.
relation is version of URL
http://doi.org/10.1016/S0009-2614(02)00641-3
department
Graduate School of Science