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ID 37377
file
creator
Honkawa, Yoshiki
Ohashi, Kazuhiko
Nishi, Nobuyuki
NDC
Chemistry
abstract
Infrared photodissociation spectra of aniline+–M (M=thiophene, furan and phenol) are measured in the 2700–3700 cm−1 region and analyzed by density functional theory calculations. Only a structure involving a π-type hydrogen bond is found for aniline+–thiophene. Two structural isomers are identified for aniline+–furan and aniline+–phenol, which have either a π-type or a σ-type hydrogen bond, where an amino proton of aniline+ interacts with the π-electrons or the oxygen atom of the neutral molecules, respectively. The isomer with a σ-type hydrogen bond is more stable for aniline+–phenol, while less stable for aniline+–furan.
journal title
Chemical Physics Letters
volume
Volume 376
issue
Issue 1-2
start page
244
end page
250
date of issued
2003-07-17
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2003 Elsevier B.V.
relation is version of URL
http://dx.doi.org/10.1016/S0009-2614(03)00985-0
department
Graduate School of Science