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ID 38236
file
creator
Iino, Takuro
Ohashi, Kazuhiko
Mune, Yutaka
Judai, Ken
Nishi, Nobuyuki
NDC
Chemistry
abstract
Coordination and solvation structures of the Cu+(H2O)n ions with n = 1–4 are studied by infrared photodissociation spectroscopy and density functional theory calculations. Hydrogen bonding between H2O molecules is detected in Cu+(H2O)3 and Cu+(H2O)4 through a characteristic change in the position and intensity of OH-stretching transitions. The third and fourth waters prefer hydrogen-bonding sites in the second solvation shell rather than direct coordination to Cu+. The infrared spectroscopy verifies that the gas-phase coordination number of Cu+ in Cu+(H2O)n is two and the resulting linearly coordinated structure acts as the core of further solvation processes.
description
This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2006, available online: http://doi.org/10.1016/j.cplett.2006.06.036
This work was supported in part by “Nanotechnology Support Project” and Grant-in-Aid for Scientific Research (No. 17550014) of the Ministry of Education, Culture, Sports, Science, and Technology (MEXT), Japan.
journal title
Chemical Physics Letters
volume
Volume 427
issue
Issue 1–3
start page
24
end page
28
date of issued
2006-08-18
publisher
Elsevier B.V.
issn
0009-2614
publisher doi
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
(c) 2006 Elsevier B.V. All rights reserved.
relation is version of URL
http://doi.org/10.1016/j.cplett.2006.06.036
department
Graduate School of Science