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ID 14702
file
creator
Ohashi, Kazuhiko
Honkawa, Yoshiki
Nishi, Nobuyuki
NDC
Chemistry
abstract
The intracluster proton transfer in aniline-amine complex ions is investigated by infrared photodissociation spectroscopy and density functional theory calculations. The proton acceptors include ammonia, methylamine, dimethylamine and trimethylamine in ascending order of proton affinity. The spectra of (aniline-ammonia)+ and (aniline-methylamine)+ demonstrate the persistence of the aniline ion unit in the complexes. For (aniline-dimethylamine)+ and (aniline-trimethylamine)+, the spectra imply the transformation to the anilino radical (C6H5NH) unit, suggesting the occurrence of the proton transfer.
journal title
Chemical Physics Letters
volume
Volume 359
issue
Issue 3-4
start page
283
end page
288
date of issued
2002
publisher
Elsevier B. V.
issn
0009-2614
language
eng
nii type
Journal Article
HU type
Journal Articles
DCMI type
text
format
application/pdf
text version
author
rights
Copyright (c) 2002 Elsevier B.V.
relation is version of URL
http://dx.doi.org/10.1016/S0009-2614(02)00737-6
department
Graduate School of Science