Infrared photodissociation spectroscopy of aniline+-(water)1,2 and aniline+-(methanol)1,2

Chemical Physics Letters Volume 358 Issue 5–6 Page 419-425 published_at 2002-06-07

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Title ( eng )	Infrared photodissociation spectroscopy of aniline+-(water)1,2 and aniline+-(methanol)1,2
Creator	Honkawa Yoshiki Inokuchi Yoshiya Ohashi Kazuhiko Nishi Nobuyuki Sekiya Hiroshi
Source Title	Chemical Physics Letters
Volume	358
Issue	5–6
Start Page	419
End Page	425
Abstract	Infrared photodissociation spectra of the aniline ion solvated by water and methanol molecules are measured in the 2600–3800 cm-1 region. Substantially red-shifted and broadened transitions are distinctly observed at 3105 and 2915 cm-1 for aniline+-(H2O)1 and aniline+-(CH3OH)1, respectively, and assigned to the stretching vibration of the hydrogen-bonded NH oscillator of the aniline+ moiety. The spectra of aniline+-(H2O)2 and aniline+-(CH3OH)2 demonstrate a large perturbation to both of the NH oscillators, indicating that each NH bond is bound to a solvent molecule in the most stable structure.
Descriptions	This work was supported in part by the Joint Studies Program (2001) of the Institute for Molecular Science and the Grant-in-Aid for Scientific Research (No. 11440177) from the Ministry of Education, Culture, Sports, Science and Technology of Japan. This is a postprint of an article published by Elsevier B.V. in Chemical Physics Letters, 2002, available online: http://doi.org/10.1016/S0009-2614(02)00641-3
NDC	Chemistry [ 430 ]
Language	eng
Resource Type	journal article
Publisher	Elsevier B.V.
Date of Issued	2002-06-07
Rights	(c) 2002 Elsevier Science B.V. All rights reserved.
Publish Type	Author’s Original
Access Rights	open access
Source Identifier	[ISSN] 0009-2614 [DOI] 10.1016/S0009-2614(02)00641-3 [DOI] http://doi.org/10.1016/S0009-2614(02)00641-3 isVersionOf