包接錯体のレーザー分光 : ホスト・ゲスト錯体の包接機構の分子レベルでの解明を目指して

Laser Spectroscopic Study of Encapsulation Complexes in the Gas Phase : Molecular Level Understanding of the Encapsulation Mechanism of Host-Guest Complexes

江幡 孝之

井口 佳哉

Molecular Science

Laser spectroscopic study has been carried out for host-guest encapsulation complexes formed in supersonic jets and electrospray ionization cold 22 ion trap. The examined hosts include benzene-substituted 18-crown-6-ethers and calix[4]arene, and for the guest species rare gas atoms, neutral molecules and alkali metal cations have been chosen. Various laser spectroscopic methods are applied: for the neutral complexes the electronic spectra are observed by laserinduced fluorescence (LIF), mass-selected resonance enhanced multiphoton ionization (REMPI) and ultravioletultraviolet hole-burning (UV-UV HB) spectroscopy. The vibrational spectra are observed by infrared-ultraviolet double resonance (IR-UV DR) and fragment detected infrared photodissociation (IRPD) spectroscopy. For the ionic complexes, ultraviolet photodissociation (UVPD) and IR-UV DR spectroscopy has been applied. The obtained results are analyzed by density functional theory and first principles electronic structure calculations. We discuss how the host molecule changes its conformation or which conformer is preferred for forming stable encapsulation complex as well as the key interactions, leading to the molecular recognition.

functional molecules

host-guest complex

supersonic jet

electrospray ion trap

laser spectroscopy

crown ether

calixarene

quantum chemical calculation

化学 [ 430 ]

日本語

分子科学会

Copyright (c) 2012 分子科学会

[ISSN] 1881-8404

[DOI] 10.3175/molsci.6.A0051

[DOI] http://doi.org10.3175/molsci.6.A0051