Anomalous cage effect in the excited state dynamics of catechol in the 18C6-catecol host-guest complex

Journal of Physical Chemistry B 119 巻 6 号 2557-2565 頁 2015-02-12 発行
アクセス数 : 1099
ダウンロード数 : 261

今月のアクセス数 : 4
今月のダウンロード数 : 1
ファイル情報(添付)
JPhysChemB_2015_119_2557.pdf 1.32 MB 種類 : 全文
タイトル ( eng )
Anomalous cage effect in the excited state dynamics of catechol in the 18C6-catecol host-guest complex
作成者
Morishima Fumiya
Kusaka Ryoji
収録物名
Journal of Physical Chemistry B
119
6
開始ページ 2557
終了ページ 2565
抄録
We present the structure of 18C6-catechol host-guest complex and the effect of the complexation on the S1 dynamics of catechol studied under a supersonically cooled gas phase condition and in cyclohexane solution. In the gas phase bare catechol, two adjacent OH groups have an intramolecular hydrogen-bonded structure. On the other hand, in the 18C6-catechol (1:1) complex both of the catechol OH groups are hydrogen-bonded to the oxygen atoms of 18C6. This complex formation greatly changes the character of the S1 state of catechol. That is, the S1 lifetime of bare catechol is reported to be 7 ps, while the 18C6-catechol complex was obtained to be 10.3 ns. This anomalous S1 lifetime elongation of catechol upon the complexation is attributed to a large energy gap between the S1 (ππ*) and S2 states by the switching from the intramolecular hydrogen-bond to the intermolecular hydrogen-bond in the host-guest complex. The formation of the18C6-catechol complex formation was also confirmed in cyclohexane solution, and an anomalous increase of fluorescence quantum yield of catechol was also observed. From the concentration dependence of the fluorescence intensity, it was confirmed that 18C6 and catechol also form (1:1) host-guest complex in bulk system. An equilibrium constant for the18C6 + catechol ⇄ 18C6・・・catechol reaction was obtained. It is suggested that that 18C6 can act as a sensor of detecting catechol.
内容記述
This is a preprint of an article published by American Chemical Society in Journal of Physical Chemistry B, 2015, available online: http://pubs.acs.org/doi/abs/10.1021/jp508619f.
NDC分類
化学 [ 430 ]
言語
英語
資源タイプ 学術雑誌論文
出版者
American Chemical Society
発行日 2015-02-12
権利情報
Copyright (c) 2014 American Chemical Society
出版タイプ Author’s Original(十分な品質であるとして、著者から正式な査読に提出される版)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 1520-6106
[DOI] 10.1021/jp508619f
[DOI] http://dx.doi.org/10.1021/jp508619f ~の異版である
[PMID] 25350575