Microhydration Effects on the Intermediates of the (I- + CH3I) SN2 Reaction <Solvent Effect>
Angewandte Chemie International Edition Volume 52 Issue 16
Page 4380-4383
published_at 2013-01-30
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| File | |
| Title ( eng ) |
Microhydration Effects on the Intermediates of the (I- + CH3I) SN2 Reaction <Solvent Effect>
|
| Creator |
Doi Keisuke
Togano Eijiro
Xantheas Sotiris S.
Nakanishi Ryuzo
Nagata Takashi
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| Source Title |
Angewandte Chemie International Edition
|
| Volume | 52 |
| Issue | 16 |
| Start Page | 4380 |
| End Page | 4383 |
| Abstract |
Hydrated I-(CH3I) complexes, I-(CH3I)(H2O)1-3, are investigated by IR photodissociation spectroscopy for examining the stable structures of the intermediates of the (I- + CH3I → ICH3 + I-) SN2 reaction under hydrated conditions. The structures and the energetics of the complexes suggest that just one or two H2O molecules will effectively inhibit this SN2 reaction.
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| Keywords |
halides
IR spectroscopy
SN2 reactions
solvent effects
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| NDC |
Chemistry [ 430 ]
|
| Language |
eng
|
| Resource Type | journal article |
| Publisher |
Wiley-VCH Verlag GmbH
|
| Date of Issued | 2013-01-30 |
| Rights |
Copyright (c) 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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| Publish Type | Author’s Original |
| Access Rights | open access |
| Source Identifier |
http://doi.org/10.1002/anie.201207697
isVersionOf
[ISSN] 1521-3773
[NCID] AA11614189
[DOI] 10.1002/anie.201207697
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