Thermoelectric properties of a clathrate compound Ba8Cu16P30

Applied Physics Letters 82 巻 16 号 2640-2642 頁 2003-04-21 発行
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タイトル ( eng )
Thermoelectric properties of a clathrate compound Ba8Cu16P30
作成者
Huo Dexuan
Sasakawa Tetsuya
Muro Yuji
収録物名
Applied Physics Letters
82
16
開始ページ 2640
終了ページ 2642
抄録
We report the electrical resistivity (ρ), thermoelectric power (S), thermal conductivity (κ), and specific heat (C) for the clathrate compound Ba8Cu16P30
in which polyhedral cages are composed of Cu and P atoms. Being in contrast to the n-type conduction in most of clathrate compounds, a p-type metallic conduction in this compound is indicated by the positive S, which monotonically increases up to 65 μV/K at 460 K. The analysis of C(T) gives indirect evidence for low-frequency local vibrations of Ba atoms with two Einstein temperatures 120 and 90 K, respectively. These local vibrations lead to a low lattice thermal conductivity of 2.9 W/K m at 300 K. The combination of the metallic resistivity, large thermoelectric power, and low thermal conductivity, makes this compound be a prospective thermoelectric material.
言語
英語
資源タイプ 学術雑誌論文
出版者
American Institute of Physics
発行日 2003-04-21
権利情報
Copyright (c) 2003 American Institute of Physics.
出版タイプ Version of Record(出版社版。早期公開を含む)
アクセス権 オープンアクセス
収録物識別子
[ISSN] 0003-6951
[DOI] 10.1063/1.1568819
[NCID] AA00543431
[DOI] http://dx.doi.org/10.1063/1.1568819